The former device exhibited the best PCE of 0 013% with the Jsc o

The former device exhibited the best PCE of 0.013% with the Jsc of 77 μA/cm2, while the PCE for the Vorinostat supplier latter suddenly decreased, which may have resulted from the degradation of polymer. Figure 6 XRD spectra (a) and I-V characteristics of P3HT/CIGS NC hybrid PV (b) with and without thermal annealing. (a) devices with and without thermal annealing; (b) P3HT/CIGS NC hybrid PV at different annealing conditions. Conclusions This work investigated and discussed on the bulk heterojunction of solar cell based on the P3HT/CIGS NC hybrid active layer. Approaches such as blend ratios of CIGS NCs, solvent effects on the morphologies, interface between P3HT/CIGS NCs, and device thermal treatments have been investigated

to enhance the power-conversion efficiency of the hybrid solar cells in detail. The best performance of devices was fabricated from a blend ratio of 1 to 3 by weight in P3HT to CIGS NCs, dichlorobenzene as solvent, pyridine as surfactant, yielding the highest PCE of approximately 0.017%. Acknowledgments This research was supported by the National compound screening assay Science Council through Grant no. EVP4593 in vitro 101-2622-E-007-011-CC2, 101-2622-E-492-001-CC2, NSC 101-2218-E-007- 009-MY3, NSC 100-2628-E-007-029-MY2, NSC 101-2623-E-007-013-IT, and the National Tsing Hua University through Grant no. 102N2022E1, 102N2051E1, and 102N2061E1. Y.L. Chueh greatly appreciates the use of facility at CNMM, National

Tsing Hua University through Grant no. 102N2744E1. References 1. Coakley KM, McGehee MD: Conjugated polymer photovoltaic cells. Chem Mater 2004, 16:4533–4542.CrossRef 2. Cheng Y-J, Yang S-H, Hsu C-S: Synthesis of conjugated polymers for organic solar cell applications. Chem Rev 2009, 109:5868–5923.CrossRef 3. Shaheen SE, Radspinner R, Peyghambarian N, Jabbour GE: Fabrication of bulk heterojunction plastic solar cells by screen printing. Appl Phys Lett 2001, 79:2996–2998.CrossRef 4. Krebs FC: Polymer solar cell modules prepared using roll-to-roll methods: knife-over-edge coating, slot-die coating and screen printing. Sol Energ Mater Sol NADPH-cytochrome-c2 reductase Cell 2009, 93:465–475.CrossRef 5. Zhou Y, Eck M, Kruger M: Bulk-heterojunction

hybrid solar cells based on colloidal nanocrystals and conjugated polymers. Energ Environ Sci 2010, 3:1851–1864.CrossRef 6. Alivisatos AP: Semiconductor clusters, nanocrystals, and quantum dots. Science 1996, 271:933–937.CrossRef 7. Boucle J, Ravirajan P, Nelson J: Hybrid polymer-metal oxide thin films for photovoltaic applications. J Mater Chem 2007, 17:3141–3153.CrossRef 8. Xu T, Qiao Q: Conjugated polymer-inorganic semiconductor hybrid solar cells. Energ Environ Sci 2011, 4:2700–2720.CrossRef 9. Beek WJE, Wienk MM, Janssen RAJ: Hybrid polymer solar cells based on zinc oxide. J Mater Chem 2005, 15:2985–2988.CrossRef 10. Lin Y-Y, Chu T-H, Li S-S, Chuang C-H, Chang C-H, Su W-F, Chang C-P, Chu M-W, Chen C-W: Interfacial nanostructuring on the performance of polymer/TiO2 nanorod bulk heterojunction solar cells. J Am Chem Soc 2009, 131:3644–3649.

Comments are closed.